No; On.Live uses ONL tokens as internal account settlement currency, meaning you have to buy tokens before you purchase a service on the website.
ONL tokens are easily bought, and can be purchased by going to the add funds option on the drop down menu at the top of the On.Live website. Once there, you can use one of over 200 payment methods to purchase tokens, including credit cards, internet money transfer services, and cryptocurrencies including Bitcoin, Ethereum, Litecoin, and Dash.
One these tokens have been purchase, you can pay for any service on your platform. If you are selling your services, you can withdraw your money from our platform to your bank account at any time.